Metallographic Etchants

Ceramic Etchants

CAUTION: Safety is very important when etching. Be sure to wear the appropriate protective clothing and observe all WARNINGS on chemical manufacturers MSDS. Also review COMMENTS Section for each etchant.

Oxide Ceramics

Etchant

Conc.

Conditions

Comments

Thermal etching in air


Minutes to hours at 100-200°C below the sintering temperature

AL2O3,
Al2O3-MgO

Molten Salt
Potassium hydrogen fluoride melt


5-10 minutes in Pt crucible

Al2O3,
Al2SiO5

Distilled water
Phosphoric acid

15 ml
85 ml

Boiling for 5 minutes to
2 hours

Al2O3

Distilled water
Sulfuric acid

50 ml
50 ml

Boiling for 1-5 minutes

ZrO2


Carbide Ceramics

Etchant

Conc.

Conditions

Comments

Molten Salt
Sodium or potassium bicarbonate melt


10 minutes in Pt crucible

SiC

Hydrochloric acid
Hydrogen peroxide (30%)

10 ml
10 ml

Seconds to minutes

WC


Nitride Ceramics

Etchant

Conc.

Conditions

Comments

Thermal etching in high purity nitrogen

 

Several hours at 1600° C

Si3N4

Molten Salt
Potassium hydroxide melt

 

Seconds to minutes in Pt crucible

Si3N4


Hydrofluoric acid

100%

10-15 minutes

Si3N4


Boride Ceramics

Etchant

Conc.

Conditions

Comments

Latic acid
Nitric acid
Hydrofluoric acid

30 ml
10 ml
10 ml

Seconds to minutes

ZrB2 ,TiB2


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