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3% Nital

General Purpose

Composition

3% Nitric Acid in Ethanol

3%

Method

Immersion

Time

5–20 s

Alternative Names

3% Nitric AcidNital 3%

Tags

carbon-steelmedium-carbon-steellow-alloy-steel

Reveals

Ferrite grain boundaries; pearlite; bainite; tempered martensite (moderate contrast)

Typical Results

Slightly more aggressive than 2% Nital. Preferred for tempered martensite, fine bainite, and medium-alloy quench-and-tempered steels (4140, 4340, 8620) where 2% under-etches.

Application Method

Method:Immersion
Typical Time:5–20 s

Preparation Notes

Mix 3 ml concentrated nitric acid (HNO₃) with 97 ml ethanol. Add acid to ethanol slowly with stirring.

Application Notes

Immerse 5–20 s at room temperature. Swab gently if attack is uneven. Rinse with ethanol, then water; air-dry.

Troubleshooting

Over-etch on low-C steels: drop back to 2%. Under-etch on hardened tool steels: switch to 5% or to Vilella's.

Storage Notes

Tightly capped amber glass at room temperature. Stable 3–6 months.

Alternative Etchants

  • 2% Nital
  • 5% Nital
  • 4% Picral

Similar Etchants

  • 2% Nital
  • 5% Nital

ASTM References

ASTM E407 #74