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5% Nital

General Purpose

Composition

5% Nitric Acid in Ethanol

5%

Method

Immersion

Time

3–15 s

Alternative Names

5% Nitric AcidNital 5%

Tags

alloy-steeltool-steeltempered-martensiteprior-austenite-grain-boundaries

Reveals

Prior austenite grain boundaries in tempered martensite; tempered martensite needle structure; fine bainite; carbides at boundaries

Typical Results

Used for prior-austenite grain boundary revealing in tempered martensitic alloy steels (4140, 4340, 8620, AISI O1). Over-etches normalized low-carbon steel; use 2% or 3% Nital there. Below 5% if the prior austenite grain boundaries are very fine.

Application Method

Method:Immersion
Typical Time:3–15 s

Preparation Notes

Mix 5 ml concentrated nitric acid with 95 ml ethanol. Add acid slowly to ethanol.

Application Notes

Immerse 3–15 s at room temperature. Start short; 5% is aggressive on softer steels. Rinse with ethanol then water; air-dry.

Troubleshooting

Whole-surface darkening: too long; drop to 3% or shorten dwell. Failed PAGB reveal: re-temper at lower temperature, or use a picric-acid-based PAGB etch.

Storage Notes

Tightly capped amber glass. Stable 3–6 months.

Alternative Etchants

  • 3% Nital
  • Vilella's Reagent
  • 4% Picral

Similar Etchants

  • 3% Nital
  • 8% Nital

ASTM References

ASTM E407 #74