Skip to main content

Al-NaOH Etchant

Material Specific

Composition

10-20g NaOH, 100ml H₂O

10-20%

Method

Immersion (warm)

Time

30–60 s at 50–70 °C

Alternative Names

Sodium HydroxideNaOH

Tags

aluminumaluminum-alloymacroetchforgingsweld-cross-section

Reveals

Macroscopic grain structure; forging flow lines; segregation; weld fusion zone and HAZ in aluminum

Typical Results

Sodium-hydroxide caustic macroetch for aluminum. Reveals grain structure on as-cast and forged sections, weld fusion / HAZ outlines, and as-rolled flow patterns. Not for micro grain-boundary work; use Keller's or 0.5% HF there.

Application Method

Method:Immersion (warm)
Typical Time:30–60 s at 50–70 °C

Preparation Notes

CAUTION: NaOH is caustic. Dissolve 10-20g NaOH in 100ml water. Use at 50°C.

Application Notes

Heat to 50–70 °C in PE container. Immerse 30–60 s. Rinse with water, then dip briefly in 25% HNO3 to desmut (removes the black film), then rinse again and air-dry.

Troubleshooting

Black smut on surface is expected; that's what the desmut step removes. Pitting on edges: solution too hot or time too long.

Storage Notes

PE or PP bottle. Stable indefinitely. Heat in the same container; do not heat in glass.

Alternative Etchants

  • Tucker's Reagent (macro)
  • Keller's Reagent (micro)

Similar Etchants

  • NaOH macroetch variants

ASTM References

ASTM E340ASTM E407 #4