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Ammonium Hydroxide + H₂O₂

Material Specific

Composition

50ml NH₄OH, 50ml H₂O₂ (3%)

50:50

Method

Immersion

Time

20s

Alternative Names

NH₄OH + H₂O₂Ammonia Peroxide

Tags

coppercopper-alloybrass

Reveals

Grain boundaries, twin boundaries

Typical Results

Standard etchant for copper and brass. Reveals grain boundaries and annealing twins. Fresh solution required for best results.

Color Effects

Grain boundaries dark, twins visible

Compatible Materials

coppercopper-alloybrass

Incompatible Materials

steelaluminum

Application Method

Method:immersion
Typical Time:20 seconds

Preparation Notes

Mix 50ml ammonium hydroxide (NH₄OH) with 50ml hydrogen peroxide (3% H₂O₂). Prepare fresh solution - decomposes quickly.

Application Notes

Immerse sample for 10-30 seconds. Swab gently if needed. Rinse with water. Fresh solution works best.

Troubleshooting

Solution decomposes quickly - prepare fresh for each use. If no etching occurs, prepare new solution. Very common and effective for copper.

Storage Notes

Cannot be stored - prepare fresh for each use. Decomposes within hours.

Alternative Etchants

  • Ammonium Persulfate
  • ASTM No. 30

Similar Etchants

  • Ammonium Persulfate
  • ASTM No. 30

ASTM References

ASTM E407