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Aqua Regia

Material Specific

Composition

75ml HCl, 25ml HNO₃

Mixed

Method

Immersion

Time

30s

Alternative Names

Royal WaterNitrohydrochloric Acid

Tags

stainless-steelnickel-alloyplatinumgold

Reveals

Grain boundaries, phases, carbides

Typical Results

Very aggressive etchant for noble metals and some stainless steels. Excellent for revealing grain structure in difficult-to-etch materials.

Color Effects

Grain boundaries dark, phases visible

Compatible Materials

stainless-steelnickel-alloyplatinumgoldpalladium

Incompatible Materials

carbon-steelaluminumtitanium

Application Method

Method:immersion
Typical Time:30 seconds

Preparation Notes

CAUTION: Extremely corrosive and produces toxic fumes. Mix 75ml concentrated HCl with 25ml concentrated HNO₃. Always add nitric acid to hydrochloric acid slowly. Prepare fresh - decomposes rapidly. Use in fume hood.

Application Notes

Immerse sample for 30-60 seconds. Swab gently if needed. Rinse immediately with copious water, then ethanol. Very aggressive - monitor closely.

Troubleshooting

Produces toxic chlorine and nitrosyl chloride fumes. Use only in fume hood with proper PPE. Prepare fresh for each use as it decomposes quickly. Very aggressive - may over-etch if left too long.

Storage Notes

Cannot be stored - prepare fresh for each use. Decomposes within hours. Store component acids separately.

Alternative Etchants

  • Glyceregia
  • Kalling's No. 2

Similar Etchants

  • Glyceregia

ASTM References

ASTM E407