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Carpenters

Material Specific

Composition

Ethyl alcohol 35–55%, Hydrogen chloride 35–55%, Nitric acid 2–5%, Ferric chloride 1–5%

PACE product, by weight

Method

Swab

Time

5–30 s

Alternative Names

Carpenter's Reagent

Tags

tool-steelhigh-speed-steelmartensitic-stainlessPH-stainless

Reveals

Carbides (M6C, MC, M23C6), prior austenite grain boundaries, and tempered martensite in tool/high-speed steels and hardened martensitic stainless

Typical Results

Classical Carpenter Steel Co. formulation: FeCl3 + CuCl2 + HCl + HNO3 + denatured ethanol. One of the most aggressive of the stainless / tool-steel family. Reveals carbide morphology and prior-austenite grain size in fully hardened tool steels (M2, T1, D2, A2, S7) and martensitic stainless.

Application Method

Method:Swab
Typical Time:5–30 s

Preparation Notes

PACE Carpenter's is supplied ready-to-use. Composition (by weight):

IngredientCAS No.%Hazardous
Ethyl alcohol64-17-535–55%Yes
Hydrogen chloride7647-01-035–55%Yes
Nitric acid7697-37-22–5%Yes
Ferric chloride7705-08-01–5%Yes
Copper (II) chloride7447-39-40.5–1.5%Yes
Methyl alcohol67-56-10–5%Yes
Isopropyl alcohol67-63-00–2%Yes

Application Notes

Swab 5–30 s at room temperature. Rinse with water, then ethanol.

Troubleshooting

Solution depletes faster than Kalling-family etchants because of the HNO3 content. Discard when color darkens significantly or smell of NOx develops. Pitted attack from over-dwell on one spot.

Storage Notes

Amber glass at room temperature. Stable a few weeks; replace when very dark or NOx-smelling.

Alternative Etchants

  • Vilella's Reagent
  • Adler's Etchant
  • Kalling's No. 2

Similar Etchants

  • Adler's Etchant
  • Vilella's Reagent

ASTM References

ASTM E407