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Weck's Etch

Material Specific

Composition

100ml Hâ‚‚O, 4g KMnOâ‚„, 4g NaOH

4% each

Method

Immersion (warm)

Time

30–120 s at 60–80 °C

Alternative Names

Weck's Reagent

Tags

aluminumaluminum-alloymagnesiummagnesium-alloyzinccolor-etchingtint

Reveals

Color-tinted grains in Al, Mg, and Zn alloys (orientation-dependent under polarized light); second-phase particles (Al-Si eutectic, Mg17Al12); grain structure in castings

Typical Results

Weck's color etchant (KMnO4 + NaOH in water) for aluminum, magnesium, and zinc alloys. Particularly effective on cast Al-Si alloys (319, 356, 380) and Mg-Al castings (AZ91, AM60), distinguishing alpha-Mg from Mg17Al12. NOT a stainless etchant; use Beraha's or Klemm's for steels.

Application Method

Method:Immersion (warm)
Typical Time:30–120 s at 60–80 °C

Preparation Notes

Dissolve 4g KMnO₄ and 4g NaOH in 100ml water. Heat to 60°C.

Application Notes

Heat solution to 60–80 °C. Immerse polished sample 30–120 s. Rinse with water then ethanol; air-dry only (compressed air re-deposits residue).

Troubleshooting

View under polarized light with a sensitive tint plate to see the orientation color contrast. Over-etch produces uniform dark; repolish and re-etch shorter. KMnO4 stains skin and bench; handle in tray.

Storage Notes

Amber glass at room temperature. Prepare fresh weekly; KMnO4 degrades, especially after heating.

Alternative Etchants

  • Barker's Reagent (Electrolytic) for Al
  • Klemm's Reagent for Mg, Zn

Similar Etchants

  • Klemm's Reagent
  • Barker's Reagent (Electrolytic)

ASTM References

ASTM E407