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Winsteard's Reagent

Material Specific

Composition

Ethyl alcohol 80–90%, Hydrogen chloride 2–5%, Picric acid 0.5–1.5%, Methyl alcohol 0.5–5%

PACE product, by weight

Method

Immersion or swab

Time

10–60 s

Alternative Names

Winsteard's Etchant

Tags

martensitic-stainlessPH-stainlesstool-steelhigh-speed-steel

Reveals

Prior austenite grain boundaries, tempered martensite, carbides in martensitic SS (410, 420, 440C), PH stainless (17-4 PH, 15-5 PH), and hardened tool/HSS

Typical Results

Vilella's-family etchant (picric + HCl + denatured ethanol) with sodium tridecylbenzene sulfonate added as a surfactant/wetting agent. The wetting agent reduces surface tension and produces more uniform attack on hydrophobic polished surfaces than straight Vilella's. Use case identical to Vilella's: prior-austenite grain boundary reveal in hardened martensitic / PH stainless and tool / high-speed steels.

Application Method

Method:Immersion or swab
Typical Time:10–60 s

Preparation Notes

PACE Winsteard's Reagent is supplied ready-to-use. Composition (by weight):

IngredientCAS No.%Hazardous
Ethyl alcohol64-17-580–90%Yes
Hydrogen chloride7647-01-02–5%Yes
Picric acid88-89-10.5–1.5%Yes
Water7732-18-50.5–1.5%No
Methyl alcohol67-56-10.5–5%Yes
Isopropyl alcohol67-63-00.5–5%Yes
Sodium tridecylbenzene sulfonate (40% solution)26248-24-84–5%No

Application Notes

Immerse or swab 10–60 s at room temperature. Rinse with ethanol, then water; air-dry.

Troubleshooting

PICRIC ACID: never let solution dry. Dry picric crystals are shock-sensitive explosives. Keep ≥0.5% water in container at all times. The surfactant reduces surface tension, so solution may bead-and-run on overly horizontal surfaces.

Storage Notes

Amber glass at room temperature; keep wet. Inspect monthly and add water if level drops. EXPLOSIVE WHEN DRY. Stable months when wet.

Alternative Etchants

  • Vilella's Reagent
  • Adler's Etchant
  • Carpenter's

Similar Etchants

  • Vilella's Reagent

ASTM References

ASTM E407