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Metallographic Etching Consumables

Etching is a critical step in metallographic specimen preparation used to reveal the microstructural features of metals and alloys. By selectively attacking different phases or grain boundaries, etchants enhance contrast and make structures like grains, inclusions, and phase distributions visible under the microscope.

Etching Consumables

Etching Product Descriptions

Compositions and applications for our most commonly used etchants, listed alphabetically. All products are available in standard 250 ml bottles unless otherwise noted.

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Etchant Composition Concentration Conditions Comments
Adler EtchantHCl, Copper ammonium chloride, FeCl3, water60-75%, 20-30%, 10-20%, 2-5%Immersion300 series stainless steel, superalloys
Al-NaOH EtchantWater, NaOH85-95%, 5-15%ImmersionAluminum alloys
Ammonium Persulfate EtchantWater, (NH4)2S2O828-79%, 15-25%ImmersionCopper and brass alloys
ASTM No. 30NH4OH, water, H2O221-72%, 28-79%, 1-4%Swab 5-45 secCopper and copper alloys; mix fresh (H₂O₂ degrades quickly)
ASTM 97Water, KOH50-60%, 40-50%Electrolytic, 2.5VFe-Cr-Ni alloys
ASTM No. 157HCl, water, CrO340-70%, 25-50%, 10-25%ImmersionHastelloy
Beraha'sWater, Na2S2O3, K2S2O585-95%, 5-15%, 2-5%ImmersionTool steel - colors ferrite, martensite, etc.
Carpenter'sEthanol, HCl, HNO3, FeCl3, methanol, IPA, CuCl235-55%, 35-55%, 2-5%, 1-5%, 0-5%, 0-2%, 0.5-1.5%Immersion, 20°CDuplex and 300 stainless steels
Copper No.1Water, HNO365-70%, 30-35%Immersion, 20°CCopper and brass
Copper No.2Water, HCl, FeCl367-85%, 10-15%, 5-10%Immersion, 20°CCopper and brass
CU-PASS-SOLCuSO4·5H2O, H2SO4, DI Water40g, 1.5ml, 245mlSwab applicationDetects free iron on stainless steels
DichromateWater, H2SO4, NaCl, K2Cr2O780-90%, 5-10%, 2-10%, 2-5%Immersion, seconds to minutesFor Cu-Sn (tin bronze)
Fry's EtchantEthanol, HCl, water, methanol, IPA, CuCl255-70%, 30-50%, 5-15%, 1-5%, 1-5%, 0.4-2%Immersion, 20°CMartensitic and PH stainless steels
Inconel EtchantHCl, water, HNO3, H2O220-40%, 10-50%, 10-30%, 10-20%Use fresh onlyMacro etch for Ni alloys
Kalling's No. 2CuCl2, HCl, Ethanol5g, 100ml, 100mlImmersion/Swab, 20°CDuplex, Ni-Cu superalloys
Keller'sWater, HNO3, HCl, HF90-95%, 5-10%, 5-10%, 1-5%10-30 sec immersionAluminum and titanium
Klemm's ReagentWater, Na2S2O3, K2S2O570-85%, 25-50%, 5-10%Seconds to minutesBrass, bronze, cast iron, steel; shares SDS with Klemm's 2
Klemm's 2Water, Na2S2O3, K2S2O570-85%, 25-50%, 5-10%Up to minutes at 40°CCopper, cast iron, tin; shares SDS with Klemm's Reagent
Kroll'sWater, HNO3, HF90-95%, 4-8%, 1-5%Swab up to 20 secTitanium and alloys
Marble'sWater, HCl, CuSO470-85%, 10-20%, 2-10%Swab or immerse 5-60 secNi, Ni-Cu, Ni-Fe superalloys
Murakami'sK3Fe(CN)6, KOH, Water10g, 10g, 100mlMix KOH + Water firstCarbides, Cr, Mo, WC-Co alloys
Nickel EtchantWater, HNO3, H2SO4, NaCl50-70%, 20-40%, 2-10%, 2-10%ImmersionMacro etch for nickel and Ni-base alloys
NitalEthanol, HNO3, methanol, IPA85-98%, 1-8%, 1-5%, 1-5%Seconds to minutesCommon Fe, steel etchant; HNO3 % varies by SKU (NITAL-2 through NITAL-8)
Oberhoffer's ReagentEthanol, Water, HCl, FeCl3, SnCl240-48%, 40-48%, 2-5%, 2-4%, 0.01-0.1%ImmersionPhosphorus segregation in low-carbon steels and cast irons
PicralEthanol, picric acid, methanol, IPA, water80-90%, 8-12%, 0.5-5%, 0.5-5%, 0.5-1.5%Seconds to minutesFerrite, carbide, bainite, etc.
Titanium Attack Polish (TI-AP-16)Water, amorphous silica, NH4OH, H2O240-60%, 30-50%, 7-12%, 0.1-1%Final polishing on napped padChemomechanical attack polish for titanium alloys (colloidal silica base)
Vilella'sEthanol, HCl, picric acid, methanol, IPA, water80-90%, 2-5%, 0.5-1.5%, 0.5-5%, 0.5-5%, 0.5-1.5%Seconds to minutesFerrite-carbide in steels; contains picric acid
Waterless Kalling'sHCl, ethanol, CuCl2, methanol, IPA40-55%, 40-55%, 0.5-10%, 0.5-2%, 0.5-2%Immersion or swabIron-base and nickel-base superalloys; concentrated HCl-in-denatured-ethanol (no water) for moisture-sensitive samples
Weck'sWater, ammonium bifluoride, HCl>85%, 10%, 0.04-0.4%Seconds to minutesTint etch for Ti alloys
Winsteard's ReagentEthanol, HCl, picric acid, methanol, IPA, sodium tridecylbenzene sulfonate, water80-90%, 2-5%, 0.5-1.5%, 0.5-5%, 0.5-5%, 4-5%, 0.5-1.5%Immersion or swabMacro etch for chromium and stainless steels; contains picric acid

Etchants by Material

Below is a summary of our most commonly used etchants, categorized by material type. All products are available in standard 250 ml bottles unless otherwise noted.

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Stainless Steels

DescriptionApplicationCatalog Number
Adlers300 Series Austenitic Stainless SteelADLERS
Carpenters300 Series Stainless SteelCARPENTERS
Kalling's No. 2Martensitic 400 Series Stainless SteelsKALLINGS No. 2
Fry's ReagentPrecipitation Hardened Stainless SteelsFRYS Reagent

Copper and Brass

DescriptionApplicationCatalog Number
ASTM No. 30CopperASTM No. 30
Copper No. 1Copper & Brass (Nitric Acid & DI Water)COPPER No. 1
Copper No. 2Copper & Brass (HCl & Ferric Chloride)COPPER No. 2
Klemm'sStain Etch for BrassKLEMMS

Steels

DescriptionApplicationCatalog Number
2-8% NitalGeneral Steels (Non-heat Treated or Welded)NITAL-2 to NITAL-8
PicralHeat Treated SteelsPICRAL
Vilella'sFerrite-Carbide StructuresVILELLAS

Aluminum & Titanium

DescriptionApplicationCatalog Number
Keller'sAluminum AlloysKELLERS
Kroll'sTitanium AlloysKROLLS
Titanium Attack PolishCMP for TitaniumTI-AP-16

Nickel, Iron, Chromium Alloys

DescriptionApplicationCatalog Number
Marble'sNickel & Nickel-Iron AlloysMARBLES
Murakami'sChromium AlloysMURAKAMIS
Waterless Kalling'sIron-Base & Nickel-Base SuperalloysWATERLESS KALLINGS
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